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Engineering biogeochemistry: from V.I. Vernadsky’s fundamental ideas to technological solutions
At present, it is possible to identify a number of new directions for the development of biogeochemical research, at the junction of fundamental and applied studies. A novel field of research is being formed, namely, engineering biogeochemistry, within the framework of which innovative biogeochemical technologies and technological processes based on modeling and management of ecosystematic biogeochemical cycles are being developed. The application of these innovative technologies for the restoration of disturbed and polluted impact ecosystems, in particular, polar ecosystems in the zones of operation of gas-producing enterprises, is considered. Technological examples of calculations of geoecological risks, as well as microbial contamination risks are given. A pool of the developed biogeochemical technologies and their connection with other innovative technologies within the framework of gas-producing companies is shown.
Reclamation of Donbas coal dump sites using biogeochemical technology
Due to the large volume of coal mining in the Russian Federation and other countries, there is a serious issue of the formation of waste heaps from coal dumps, which pose a significant threat to the environment of adjacent territories. One of such areas is the Donetsk coal basin, whose area is more than 60 thousand km2. Phytoreclamation is the most common and cost-effective method recommended for the restoration of degraded coal dump soil, which reduces the removal of toxic substances with dust emissions and water runoff. However, plant growth on these soils is hindered by their phytotoxicity and unfavorable physical and physicochemical properties. The aim of this research was to develop a biogeochemical technology for the reclamation of coal dumps in Donbas based on phytoreclamation with various additives. Our experiments involved soil samples taken from the upper layer of the Ayutinskaya mine waste heap in the Donetsk coal basin, as well as zonal ordinary chernozem samples. The experiments were conducted in microfield conditions in bottomless vessels with an area of 0.1 m2 dug into the ground. The additives used were wood biochar and other sorbents, including mineral (diatomite and vermiculite) and organic (acidic and neutralized peat) ones, as well as ordinary chernozem and quarry sand – clean and with biohumus additives. The soil was seeded with a drought-resistant lawn mixture. All additives had a positive effect on the growth of green mass of drought-resistant lawn, measured during 3 cuttings ib the vegetation season of 2024. However, the best results were obtained with the addition of neutralized peat and chernozem at doses of 25 %, as well as quarry sand at doses of 25 and 50 % with the addition of biohumus; at the same time, the additional addition of 5 % biochar to all these samples gave no desired result.
SILICATIZATION OF CULTURAL LAYER SOILS IN ARCHAEOLOGICAL EXCAVATIONS
The preservation and in situ museumification of archaeological objects of stratigraphic sections of cultural layer soils, whose value depends on the integrity and intactness, is a complex and underdeveloped problem. This is due to some specific properties of these soils, such as the heterogeneity of soil composition both vertically and horizontally; the diversity of inclusions, the uneven compressibility of the strata, the ability to self-compact from their weight, changes in hydrogeological conditions, soil soaking and the decomposition of organic inclusions. As a result, these soils are the most unfavorable in artificial stabilization. In the study, a wide range of soils of the cultural layer from various places with stabilization plans were examined. Our analysis of the deposits made it possible to separate these soils by geochemical features which have the highest impact on the intensity of the chemical solution’s interaction processes with the mineral component of the soil.
This chemical solution is in a family of silicate compositions with surfactants of the amide class. These organic liquid glass hardeners activate the skeletal part of the soil and provide the complete mobilization of the main cementing substance (silica gel). Pilot tests of various modifications of organo-silicate solutions were carried out at the sites of Chersonesos (Sevastopol), Tanais (Rostov region), Moscow, etc. The soils ranged from sandy to loamy with various inclusions (building stone, ceramics, bones, fish scales, shells, ash, soot, plant roots, etc.). Soil stabilization was carried out by injecting chemical solutions of various densities with the use of vertical and horizontal injections. An important finding of the work was that forming a new soil mass with improved properties was determined by the composition, properties of the soil and injection solutions, the distance from the injector and the depth of the stabilized area.
For the first time in Russia, at the center of Moscow, it was possible to preserve the soil mass in situ of the cultural layer of the 16–17th centuries and exhibit it for 32 years to visitors in the underground archaeological museum.