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Zhizn Zemli [Life of the Earth] 45, no 1

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Zhizn Zemli [Life of the Earth] 45, no 1

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DOI

10.29003/m3150.0514-7468.2023_45_1/59-65

EDN

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Authors:

Gromalova, N.A., Chekhovich, P.A.

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Keywords:

vernadite, nanocrystalline oxides, birnessite, crystal chemistry, microbial metabolism, museum collections.

vernadite, nanocrystalline oxides, birnessite, crystal chemistry, microbial metabolism, museum collections.

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pp. 59–65

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Gromalova, N.A., Chekhovich, P.A., “Vernadite as a metabolic product of microorganisms. Mineralogical specimens from the Earth Science Museum”, Zhizn Zemli [Life of the Earth] 45, no 1, 59–65 (2023) (in Russ., abstract in Engl.) DOI: 10.29003/m3150.0514-7468.2023_45_1/59-65.

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Vernadite as a metabolic product of microorganisms. Mineralogical specimens from the Earth Science Museum”

17.03.2026

Brief information is given about the samples of vernadite from the mineralogical collection of the Earth Science Museum, which were passed for display at the exhibition organized for the anniversary of V.I. Vernadsky. The history of the discovery and studying of vernadite and features of its chemism, modern concepts of its crystal structure, genesis as well as some practical applications are addressed. Attribution of the exhibition samples as vernadites is questionable due to the lack of information about their instrumental diagnostics.

References

Список литературы

Список литературы

  1. Betekhtin, A.G., “On new mineral species of the manganese hydroxide group”, Proc. of the Russian Mineralogical Soc. 66, no 4, 703–712 (1937) (in Russian).
  2. Betekhtin, A.G., “Manganese deposits of Yuzhnouralsk as a resource base for the Stalin Magnitogorsk Iron and Steel Works”, Proc. of the Institute of Geol. Sciences. Ser. of ore deposits 30, no 4, 63 p. (1940) (in Russian).
  3. Drits, V.A., Salyn, A.L., “Crystal-chemical nature of oceanic formations of Fe-Mn vernadites”, Mineral. Mag. 10, no 2, 78–92 (1988) (in Russian).
  4. Pekov, I.V., Lovozero massif: history of research, pegmatites, minerals. (Мoscow: Zemlya, 2001) (in Russian).
  5. Chukhrov, F.V., Gorshkov, A.I., Rudnitskaya, E.S., Beresovskaya, V.V., Sivtsov, A.V., “Manganese minerals in clay: a review”, Clays and Clay Minerals 28, 346–453 (1980).
  6. Giovanoli, R., “Vernadite is random-stacked birnessite”, Mineralium Deposita 15, 251–253 (1980).
  7. Grangeon, S., Manceau, A., Guilhermet, J., Gaillot, A.C., Lanson, M., Lanson, B., “Zn sorption modifies dynamically the layer and interlayer structure of vernadite”, Geochim. Cosmochim. Acta 85, 302–313 (2012).
  8. Lee, S., Xu, H., Xu, W., Sun, X., “The structure and crystal chemistry of vernadite in ferromanganese crusts”, Acta Crystallographica B75, 591–598 (2019).
  9. Manceau, A., Gorshkov, A.I., Drits, V.A., “Structural chemistry of Mn, Fe, Co, and Ni in manganese hydrous oxides: Part II. Information from EXAFS spectroscopy and electron and X-ray diffraction”, Amer. Mineral 77, 1144–1157 (1992).
  10. Manceau, A., Lanson, M., Geoffroy, N., “Natural speciation of Ni, Zn, Ba, and As in ferromanganese coatings on quartz using X-ray fluorescence, absorption, and diffraction”, Geochim. Cosmochim. Acta 71, 95–128 (2007).
  11. Manceau, A., Marcus, M. A., Grangeon, S., Lanson, M., Lanson, B., Gaillot, A.-C., Skanthakumar, S., Soderholm, L., “Short-range and long-range order of phyllomanganate nanoparticles determined using high-energy X-ray scattering”, J. Appl. Cryst. 46, 193–209 (2013).
  12. Manceau, A., Lanson, M., Takahashi, Y., “Mineralogy and crystal chemistry of Mn, Fe, Co, Ni, and Cu in a deep-sea Pacific polymetallic nodule”, Am. Mineral. 99, 2068–2083 (2014).
  13. Ostwald, J., “Ferruginous vernadite in an Indian Ocean ferromanganese nodule”, Geol. Mag. 121, 483–488 (1984).
  14. Simonin, L., Colin, J.-F., Ranieri, V., Cane´ vet, E., Martin, J.-F., Bourbon, C., Baehtz, C., Strobel, P., Daniel, L., Patoux, S.,“In situ investigations of a Li-rich Mn–Ni layered oxide for Li-ion batteries”, J. Mater. Chem. 22, 11316–11322 (2012).
  15. Tebo, B.M., Barga, J.R., Clement, B.G., Dick, G.J., Murray, K.J., Parker, D., Verity, R., Webb, S.M., “Biogenic manganese oxides: properties and mechanisms of formation”, Annu. Rev. Earth Planet. Sci. 32, 287–328 (2004).
  16. Varentsov, I.M., Drits, V.A., Gorshkov, A.I., Sivtsov, A.V. & Sakharov, B.A., “Mn-Fe oxyhydroxide crusts from Krylov Seamount (Eastern Atlantic): Mineralogy, geochemistry and genesis”, Mar. Geol. 96, 53–70 (1991).

References

  1. Betekhtin, A.G., “On new mineral species of the manganese hydroxide group”, Proc. of the Russian Mineralogical Soc. 66, no 4, 703–712 (1937) (in Russian).
  2. Betekhtin, A.G., “Manganese deposits of Yuzhnouralsk as a resource base for the Stalin Magnitogorsk Iron and Steel Works”, Proc. of the Institute of Geol. Sciences. Ser. of ore deposits 30, no 4, 63 p. (1940) (in Russian).
  3. Drits, V.A., Salyn, A.L., “Crystal-chemical nature of oceanic formations of Fe-Mn vernadites”, Mineral. Mag. 10, no 2, 78–92 (1988) (in Russian).
  4. Pekov, I.V., Lovozero massif: history of research, pegmatites, minerals. (Мoscow: Zemlya, 2001) (in Russian).
  5. Chukhrov, F.V., Gorshkov, A.I., Rudnitskaya, E.S., Beresovskaya, V.V., Sivtsov, A.V., “Manganese minerals in clay: a review”, Clays and Clay Minerals 28, 346–453 (1980).
  6. Giovanoli, R., “Vernadite is random-stacked birnessite”, Mineralium Deposita 15, 251–253 (1980).
  7. Grangeon, S., Manceau, A., Guilhermet, J., Gaillot, A.C., Lanson, M., Lanson, B., “Zn sorption modifies dynamically the layer and interlayer structure of vernadite”, Geochim. Cosmochim. Acta 85, 302–313 (2012).
  8. Lee, S., Xu, H., Xu, W., Sun, X., “The structure and crystal chemistry of vernadite in ferromanganese crusts”, Acta Crystallographica B75, 591–598 (2019).
  9. Manceau, A., Gorshkov, A.I., Drits, V.A., “Structural chemistry of Mn, Fe, Co, and Ni in manganese hydrous oxides: Part II. Information from EXAFS spectroscopy and electron and X-ray diffraction”, Amer. Mineral 77, 1144–1157 (1992).
  10. Manceau, A., Lanson, M., Geoffroy, N., “Natural speciation of Ni, Zn, Ba, and As in ferromanganese coatings on quartz using X-ray fluorescence, absorption, and diffraction”, Geochim. Cosmochim. Acta 71, 95–128 (2007).
  11. Manceau, A., Marcus, M. A., Grangeon, S., Lanson, M., Lanson, B., Gaillot, A.-C., Skanthakumar, S., Soderholm, L., “Short-range and long-range order of phyllomanganate nanoparticles determined using high-energy X-ray scattering”, J. Appl. Cryst. 46, 193–209 (2013).
  12. Manceau, A., Lanson, M., Takahashi, Y., “Mineralogy and crystal chemistry of Mn, Fe, Co, Ni, and Cu in a deep-sea Pacific polymetallic nodule”, Am. Mineral. 99, 2068–2083 (2014).
  13. Ostwald, J., “Ferruginous vernadite in an Indian Ocean ferromanganese nodule”, Geol. Mag. 121, 483–488 (1984).
  14. Simonin, L., Colin, J.-F., Ranieri, V., Cane´ vet, E., Martin, J.-F., Bourbon, C., Baehtz, C., Strobel, P., Daniel, L., Patoux, S.,“In situ investigations of a Li-rich Mn–Ni layered oxide for Li-ion batteries”, J. Mater. Chem. 22, 11316–11322 (2012).
  15. Tebo, B.M., Barga, J.R., Clement, B.G., Dick, G.J., Murray, K.J., Parker, D., Verity, R., Webb, S.M., “Biogenic manganese oxides: properties and mechanisms of formation”, Annu. Rev. Earth Planet. Sci. 32, 287–328 (2004).
  16. Varentsov, I.M., Drits, V.A., Gorshkov, A.I., Sivtsov, A.V. & Sakharov, B.A., “Mn-Fe oxyhydroxide crusts from Krylov Seamount (Eastern Atlantic): Mineralogy, geochemistry and genesis”, Mar. Geol. 96, 53–70 (1991).